Improving corrosion protection of Mg alloys (AZ31B) using graphene-based hybrid coatings

Main Authors: Afsharimani N., Talimian A., Merino E., Durán A., Castro Y., Galusek D.
Format: Article Journal
Bahasa: eng
Terbitan: , 2021
Online Access: https://zenodo.org/record/5569107
Daftar Isi:
  • In the present work, a study was carried out to compare the morphology andelectrochemical properties of pure and graphene-modified hybrid silica sol–gel coatings deposited on anodized AZ31B magnesium alloys. The precursorsolution was prepared using tetraethoxysilane (TEOS) and 3-glycidoxypropyl-trimethoxysilane (GPTMS), with the addition of chemically modified graphenenanosheets (GN-chem). Homogeneous and adherent coatings were obtainedusing GPTMS-TEOS (GT) and GPTMS-TEOS-GN-chem (GT/GN-chem) solu-tions with uniform thickness around 4μm. Raman, SEM images and EDS analy-ses confirmed the presence of graphene nanosheets in the coatings. Potentiody-namic polarization results using 0.05 M NaCl electrolyte solution showed thatgraphene containing silica coatings significantly improve the corrosion resis-tance of AZ31B alloys. In addition, a significant passive region was observed forGT/GN-chem coatings.
  • barrier properties, corrosion protection, graphene nanosheets, magnesium alloy, sol–gelcoatings