Quantum Mechanics and Orthonormal Basis Functions
| Main Author: | Francesco R. Ruggeri |
|---|---|
| Format: | info publication-preprint Journal |
| Terbitan: |
, 2021
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/5155900 |
Daftar Isi:
- For quantum bound states, classical style probabilities P(p)=a(p)a(p) and P(x)=W(x)W(x) [where W(x)= the wavefunction = Sum over p a(p) exp(ipx)] exist. These are real and normalized to one, but unusually, they separate p and x completely. For example, P(p) is the probability to find a momentum p anywhere in the system - no information about x is known. This seems to suggest that the P(p/x) is not defined in a classical sense. (Similar arguments hold for P(x).) We have argued in a previous note (1), that due to a lack of time reversal balance, there is no clear classical notion of P(p/x) in quantum mechanics while in classical statistical mechanics, there is a time reversal balance of two-body collisions and so P(p/x) is well-defined. In particular, a momentum p collides with a pj to form another momentum pk. There is ambiguity if p is changing, but if at the same time a pk is changing (colliding) back into a p at x, then the ambiguity is removed. In quantum mechanics, the ambiguity is not removed at x, but one may discern one p state from another throughout the entire x space. This suggests orthonormal probabilities e.g. say exp(ip1 x) and exp(i p2 x). These exp(i p x) probabilities comprise the wavefunction which is linked to P(p/x) = a(p) exp(ipx)/W(x), but although Sum over p P(p/x)=1, P(p/x) is complex with the real and complex portions taking on positive and negative values. Nevertheless, it is W(x) which is the solution of the Schrodinger (and other) equations. It is known that solutions Wn(x) of the Schrodinger equation have discrete En (energy) values. It is possible to have [H, Operator]=0 and possibly to have H written in terms of this operator. In such a case, Wn(x) might be both an eigenfunction of H and the Operator. Alternatively, a linear combination of Operator eigenfunctions may be used. If En is discrete, one may expect the operator eigenfunctions to also be discrete, leading to quantization of the Operator eigenvalues. In some cases, one may have two operators which commute with H, e.g. LL and Lz (related to angular momentum). Lz eigenfunctions might not be linked to H so one might ask why Lz should be quantized. Another H, however, may distinguish between Lz eigenfunctions and so they also have discrete eigenvalues. In this note, we try to consider why one should have orthonormal eigenfunctions of these commuting operators which make up the wavefunction and try to interpret their physical meaning.