Uncovering the Triplet Ground State of Triangular Graphene Nanoflakes Engineered with Atomic Precision on a Metal Surface
| Main Authors: | Li, Jingcheng, Sanz, Sofia, Castro-Esteban, Jesus, Vilas-Varela, Manuel, Friedrich, Niklas, Frederiksen, Thomas, Peña, Diego, Pascual, Jose Ignacio |
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| Format: | info dataset Journal |
| Terbitan: |
, 2020
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/4243077 |
Daftar Isi:
- OPEN DATA related to the research publication: J. Li, S. Sanz, J. Castro-Esteban, M. Vilas-Varela, N. Friedrich, T. Frederiksen, D. Peña, and J. I. Pascual, Uncovering the triplet ground state of triangular graphene nanoflakes engineered with atomic precision on a metal surface, Phys. Rev. Lett. 124, 177201 (2020) [arXiv:1912.08298] Abstract: Graphene can develop large magnetic moments in custom-crafted open-shell nanostructures such as triangulene, a triangular piece of graphene with zigzag edges. Current methods of engineering graphene nanosystems on surfaces succeeded in producing atomically precise open-shell structures, but demonstration of their net spin remains elusive to date. Here, we fabricate triangulenelike graphene systems and demonstrate that they possess a spin S=1 ground state. Scanning tunneling spectroscopy identifies the fingerprint of an underscreened S=1 Kondo state on these flakes at low temperatures, signaling the dominant ferromagnetic interactions between two spins. Combined with simulations based on the meanfield Hubbard model, we show that this S=1 π paramagnetism is robust and can be turned into an S=1/2 state by additional H atoms attached to the radical sites. Our results demonstrate that π paramagnetism of high-spin graphene flakes can survive on surfaces, opening the door to study the quantum behavior of interacting π spins in graphene systems.
- We acknowledge funding from the European Union's Horizon 2020 research and innovation programme under grant agreement No 863098 (FET-Open project "SPRING").