KNH2 - KH: a metal amide - hydride solid solution
| Main Authors: | Antonio Santoru, Claudio Pistidda, Magnus H. Sørby, Michele R. Chierotti, Sebastiano Garroni[, Eugenio Pinatel, Fahim Karimi, Hujun Cao, Nils Bergemann, Thi T. Le, Julián Puszkiel, Roberto Gobetto, Marcello Baricco, Bjørn C. Haub, Thomas Klassen, Martin Dornheim[ |
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| Format: | Article Journal |
| Terbitan: |
, 2016
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/4003632 |
Daftar Isi:
- We report for the first time the formation of a metal amidehydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2-ions. The rotational properties of the high-temperature polymorphs of KNH2 are thereby retained down to room temperature.