Analysis of High Resolution Infrared CW-CRDS Spectra of Ozone in the 6000 - 6750 cm -1 Spectral Region
| Main Authors: | Barbe, A, De Backer-Barilly, M. R., Tyuterev, Vl. G., Romanini, D., Kassi, S., Campargue, A. |
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| Format: | info Proceeding |
| Terbitan: |
, 2006
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/17574 |
Daftar Isi:
- The fibered Distributed Feed-Back (DFB) diode laser CW-CRDS spectrometer of LSP Grenoble, has been used to record the absorption spectrum of ozone in the 6000- 6750 cm -1 region with a typical sensitivity of à min ~3x10^-10cm^-1 . Transitions as weak as 1x10^-27 cm^-1 / mol. cm^-2 (296 K) could be detected. Removing usual impurities as H2O, CO, CO2 , a total of 5578 transitions have been assigned to 15 bands (9 A type and 6 B type). We present an overview of this work, in course, and present in detail two specific spectral ranges, where analysis are complete, that is to say 5970 - 6210 and 6640 - 6830 cm^-1 . For these regions, we give: range of assigned quantum numbers, Hamiltonian and transition moment parameters, statistics for positions and intensities and examples of agreement between observations and calculations