SYNTHESIS OF 2-SUBSTITUTEDGUANIDINO-4-SUBSTITUTED-IMINE-6-SUBSTITUTEDIMINO-1,3,5-THIADIAZINES

Main Author: P. V. Raut*, P. S. Bodakhe, S. A. Waghmare, D. T. Tayade
Format: Article
Bahasa: eng
Terbitan: , 2017
Subjects:
1
3
Online Access: https://zenodo.org/record/1069718
Daftar Isi:
  • A novel series of 2-substitutedguanidino-4-substitutedimine-6-sub-stitutedimino-1,3,5- thiadiazines (IIIa1 -e 5 ) have been recently synthesized by refluxing N-methylformamidino-N’- phenyliminothiocarbamide also called as 1-(N-substitutedcarbamimidoyl)3-{N-(E)- substitutedmethylidinecar-bamimidoyl}thiourea (Ia-e) with various isocyanodichloride (II1-5) in acetone-ethanol medium in 1:1 molar proportion. The structure of all the synthesized compounds was justified on the basis of chemical characteristics, elemental analysis and IR, NMR and mass spectral analysis. Keywords: Guanidine, 1,3,5-thiadiazines, acetone, ethanol etc