Transient Raman spectroscopy of 15N-substituted bacteriochlorophyll a. An empirical assignment of T1 Raman lines
| Main Authors: | Leenawaty, Limantara, Yasushi, Koyama, Ingrid, Katheder, Hugo, Scheer |
|---|---|
| Format: | Article PeerReviewed Book |
| Bahasa: | eng |
| Terbitan: |
Elsevier BV
, 1994
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| Subjects: | |
| Online Access: |
http://eprints.upj.ac.id/id/eprint/74/1/Transient%20Raman%20Spectroscopy.pdf http://eprints.upj.ac.id/id/eprint/74/ |
Daftar Isi:
- *sN-substituted bacteriochlorophyll a (BChl a) was extracted from the cells of Rhodobacter sphaeroides 2.4.1 grown in a medium containing 15N-ammonium sulfate and yeast concentrate. The T, Raman spectra of 14N- and “N-BChl a were obtained as the difference spectra of high-power minus low-power of one-color, pump-and-probe measurements using 420 nm, 5 ns pulses. A set of empirical assignments of the TI Raman lines was made, based on shifts upon 14N+lSN substitution. The S,, Raman spectra of the two BChls were also obtained by using the 457.9 nm cw beam, and a set of assignments of the So Raman lines was given for comparison.