SYNTHESIS AND MAGNETIC PROPERTIES OF BINUCLEAR COMPLEX [N(n-C4H9)4][MnIIFeIII(ox)3]
| Main Authors: | Martak, Fahimah; Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111, Fansuri, Hamzah; Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111, Putri, Sekarayu Dianing; Department of Chemistry, Institut Teknologi Sepuluh Nopember, Kampus ITS Sukolilo Surabaya 60111 |
|---|---|
| Format: | Article info application/pdf eJournal |
| Bahasa: | eng |
| Terbitan: |
Universitas Gadjah Mada
, 2012
|
| Subjects: | |
| Online Access: |
http://pdm-mipa.ugm.ac.id/ojs/index.php/ijc/article/view/676 http://pdm-mipa.ugm.ac.id/ojs/index.php/ijc/article/view/676/1080 |
Daftar Isi:
- Binuclear complex, [N(n-C4H9)4][MnIIFeIII(ox)3] (ox=oxalate), has been synthesized and characterized. Binuclear complex with formula of [N(n-C4H9)4][MnIIFeIII(ox)3] was synthesized by forming precursor K3[Fe(ox)3] which was followed by adding manganese chloride and tetrabutyl ammonium chloride. Characterization of the complex was made by microanalysis, FT-IR spectroscopy, x-ray diffraction and Magnetic Susceptibility Balance. Magnetic moment of binuclear complex [N(n-C4H9)4][MnIIFeIII(ox)3] is 7.81 BM. The compound has higher magnetic moment than the previously reported compound with different organic cation, [N(n-C5H11)4][MnIIFeIII(ox)3]. This behavior might be associated with the decreasing range among layers on polymeric network.